Start with the target reaction
Chlorine evolution, oxygen evolution, metal deposition or oxidation of a contaminant. The reaction decides which coating family is even worth reviewing.
The coating is the functional part of a titanium anode. This page compares the four coating systems we supply and shows which one has to be reviewed against a given process window.
How The Families Relate
Mixed metal oxide is the coating family. Ru-Ir and Ir-Ta are specific oxide combinations inside that family, not competitors to it. A Ru-Ir anode and an Ir-Ta anode are therefore both MMO anodes, and both are also MMO geometry products, because the coating chemistry and the shape of the electrode are two independent questions. The same anode can be described as an MMO titanium anode, as a Ru-Ir coated anode and as a tubular anode at the same time. Which description a buyer needs depends on whether the decision is about the surface, the shape or the application.
Chlorine evolution, electrochlorination and hypochlorite generation
Review this coating →Oxygen evolution and selected advanced oxidation duties
Review this coating →Precious metal plating, hard chrome plating and selected electrolysis
Review this coating →Advanced oxidation and project-specific electrochemical duties
Review this coating →Comparison
A coating name is not a specification. The reaction, the media, the current basis and the factor that normally limits the service life are what separate one family from another.
| Coating Family | Commonly Reviewed For | Media | Current Basis | What Limits The Life |
|---|---|---|---|---|
| Ru-Ir Mixed Metal Oxide | Chlorine evolution, electrochlorination and hypochlorite generation | Chloride brines, seawater and chloride-bearing process streams | Stated per unit of coated active area for the reviewed electrolyte | Impurity load, chloride level, pH and operating temperature |
| Ir-Ta and Ir-Based Mixed Metal Oxide | Oxygen evolution and selected advanced oxidation duties | Alkaline and acidic electrolytes, including water treatment matrices | Stated per unit of coated active area under the defined potential or current duty | Electrolyte composition, contaminant behaviour and mass transfer |
| Platinized Titanium | Precious metal plating, hard chrome plating and selected electrolysis | Plating baths and defined electrolysis media | Defined by the platinum metric, its coverage and the active area | Bath chemistry, polarity, current density and mechanical wear |
| Specialty Coated Titanium | Advanced oxidation and project-specific electrochemical duties | Case-by-case, defined by the complete process matrix | Stated per unit of coated area against a qualification basis | Defined by the pilot or qualification programme and the disposal route |
Selection Path
The order of these steps matters. Naming the coating first is what produces quotations that cannot be compared with each other.
Chlorine evolution, oxygen evolution, metal deposition or oxidation of a contaminant. The reaction decides which coating family is even worth reviewing.
Composition, concentration, contaminants, pH, temperature and flow. A coating name without the full matrix cannot be accepted as a selection.
Current, voltage, waveform, polarity, daily operating schedule and the current-density basis expressed per unit of coated active area.
Only after the surface is fixed does the shape follow from the installation. The eight MMO geometries are reviewed from their own pages.
Once the active surface is fixed, the shape follows from the installation. The eight MMO geometries — linear, wire, ribbon, mesh ribbon, canister, tubular, disc and rod — are reviewed on their own pages.
Coating Family Pages
Each coating page states the reactions it is commonly reviewed for, the inputs that change the decision and the geometry it is supplied in.
Chloride brines, seawater and chloride-bearing process streams
Review Ru-Ir Mixed Metal Oxide →Alkaline and acidic electrolytes, including water treatment matrices
Review Ir-Ta and Ir-Based Mixed Metal Oxide →Plating baths and defined electrolysis media
Review Platinized Titanium →Case-by-case, defined by the complete process matrix
Review Specialty Coated Titanium →FAQ
A Ru-Ir anode is an MMO anode: the ruthenium and iridium oxide combination is one of the mixed metal oxide systems inside the MMO family. They are described separately on this site because the coating chemistry drives the reaction it suits, not because they belong to different product categories.
Sometimes, but the comparison has to be made on the same basis. Platinum brings a different cost structure, a different wear behaviour and a different metric, so a platinized electrode should not be specified just because it is described as a more inert surface. The duty, the media and the expected wear have to be reviewed together.
Because loading and thickness are different characteristics, each with its own units, measurement method, sampling plan and acceptance criteria. A loading figure quoted without its method cannot be compared against another supplier, and a test result on one characteristic is not proof of the others.
Target reaction, electrolyte composition, contaminants, pH, temperature, current density with its active-area basis, geometry and the required life. A complete specification is not required for the first review.